Climate change is intensifying the Arctic hydrologic cycle, potentially accelerating the release of carbon and nutrients from permafrost landscapes to rivers. However, there are limited riverine flow and solute data of adequate frequency and duration to test how seasonality and catchment landscape characteristics influence production and transport of carbon and nutrients in Arctic river networks. We measured high frequency hydrochemical dynamics at the outlets of three headwater catchments in arctic Alaska over three years. The catchments represent common Arctic landscapes: low-gradient tundra, low-gradient and lake-influenced tundra, and high-gradient alpine tundra. Using in-situ spectrophotometers, we measured dissolved organic carbon (DOC) and nitrate (NO3-) concentrations at 15-minute intervals through the flow seasons of 2017, 2018, and 2019. The high-frequency data allowed us to quantify concentration-discharge (C-Q) responses during individual storm events across the flow season. Differences in C-Q responses among catchments indicated strong landscape and seasonal controls on lateral DOC and NO3- flux. For the two low-gradient tundra catchments, we observed consistent DOC enrichment (transport-limitation) and NO3- dilution (source-limitation) during flow events. Conversely, we found consistent NO3- enrichment and DOC dilution in the high-gradient alpine catchment. Our analysis also revealed how high flow events may contribute disproportionately to downstream export and highlighted the ongoing need to quantify late season export in permafrost regions. As the duration of the flow season and intensity of Arctic storms are expected to increase, understanding how discharge and solute concentration are coupled is crucial to closing carbon and nutrient budgets in rapidly changing permafrost ecosystems.
CAREER: Towards Forecasting Watershed Organic Carbon Fluxes across Flow Regimes and Ecoregions. Collaborative Research: Arctic Stream Networks as Nutrient Sensors in Permafrost Ecosystems