To determine temporal and spatial patterns in arctic stream biogeochemistry we conducted three synoptic surveys of streams throughout a 48km2 watershed near Toolik Lake, AK in spring (early-June), summer (mid-July), and fall (mid-September) 2011. During each synoptic survey, we sampled 52 sites within a period of four days to minimize the effect of temporal hydrologic variability. At each site we measured stream temperature, pH, and conductivity and sampled water for solute analysis.